Tags: Chemical Compound, Chemical Substance.

The Trost ligand is a chiral ligand pioneered by Barry Trost for use in the palladium-catalyzed Trost asymmetric allylic alkylation. Other C2-symmetric ligands derived from trans-12-diaminocyclohexane (DACH) have also been developed by the Trost group such as the (RR)-DACH-naphthyl ligand derived from 2-diphenylphosphino-1-naphthalenecarboxylic acid.

Trost_ligand.png
IUPAC name
(1R2R)-(+)-12-diaminocyclohexane-NN'-bis(2-diphenylphosphinobenzoyl)

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