Tags: Chemical Compound, Chemical Substance.
Sodium hexametaphosphate (SHMP) is a hexamer of composition (NaPO3)6. Sodium hexametaphosphate of commerce is typically a mixture of polymeric metaphosphates of which the hexamer is one and is usually the compound referred to by this name. It is more correctly termed sodium polymetaphosphate. It is prepared by melting monosodium orthophosphate followed by rapid cooling.